منابع مشابه
Unraveling the Wacker oxidation mechanisms.
The Wacker processsolefin oxidation via a Pd(II)Cl2 catalyst and an air-recyclable CuCl2 co-oxidant (Scheme 1)swas one of the most important industrial breakthroughs in the fabrication of organic chemicals, and is widely regarded as one of the quintessential organometallic processes.1 Besides its industrial importance, the Wacker process and its analogues are continually used in fields relating...
متن کاملEfficient and highly aldehyde selective Wacker oxidation.
A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl(2)(MeCN)(2), 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates.
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ژورنال
عنوان ژورنال: Nature Reviews Chemistry
سال: 2020
ISSN: 2397-3358
DOI: 10.1038/s41570-020-0181-4